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Dopamine in the cytosol is metabolized to 3-methoxytyramine by catecholamine o-methyltransferase (COMT), which uses s-adenosylmethionine as a methyl group donor.
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http://rdf.wikipathways.org/Pathway/WP3165_r117564/Comment/a684f266978e10931b8d1ca824296a71